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Smite is very complex, but with the right mindset you’ll be good. You need to figure out how you want to play the game first. Do you want to deal damage or support your team? Do you want to be long ranger or melee? Do you want to deal massive AOE or deal single target damage? Do you want to brawl in the enemies face, or fight at range? All of these come into play when choosing your character. I recommend starting with Scylla as she does a lot of AOE damage, can escape when you need to, and can be really good at higher levels of play, assuming you stick with the game. If you prefer a more single target/melee play style, try Thor. He’s the same as he can be good at lower and higher levels of play. A good starting hunter would be Neith by far. A good first brawler would be Hercules. Finally, a good support would be Kepri or Kumbakarna. Again it all depends on your play style.